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化工新型材料  2018, Vol. 46 Issue (8): 195-197    
  科学研究 本期目录 | 过刊浏览 | 高级检索 |
N′,N-二-(2-羟乙基)-草酰胺的制备方法研究
王峰, 彭丹, 牟秋红, 张方志
齐鲁工业大学山东省科学院),山东省科学院新材料研究所,山东省特种含硅新材料重点实验室,济南250014
Research on preparation of N′,N-bis(2-hydroxyethyl) oxamide
Wang Feng, Peng Dan, Mu Qiuhong, Zhang Fangzhi
Qilu University of Technology (Shandong Academy of Sciences),Advanced Materials Institute,Shandong Provincial Key Laboratory for Special Silicone-Containing Materials,Jinan 250014
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摘要 以甲醇为溶剂,草酸二乙酯与单乙醇胺为原料制备了N′,N-二-(2-羟乙基)-草酰胺,并对其进行红外光谱分析。研究溶剂用量、反应物配比、反应温度与保温时间对N′,N-二-(2-羟乙基)-草酰胺产率的影响。结果表明:最佳工艺条件为甲醇作溶剂,甲醇与草酸二乙酯质量比=5∶1,反应物摩尔比n(草酸二乙酯)∶n(单乙醇胺)=1∶2.3,反应温度为70℃,保温时间1.5h,此时N′,N-二-(2-羟乙基)-草酰胺产率达到97.1%。
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王峰
彭丹
牟秋红
张方志
关键词:  N′,N-二-(2-羟乙基)-草酰胺  合成  研究    
Abstract: N′,N-bis (2-hydroxyethyl) oxamide was prepared from diethyl oxalate and monoethanolamine in the presence of methanol as solvent.The structure of product was characterized by FT-IR.The effects of solvent amount,reaction temperature and holding time,reactant ratio on the yield were discussed.The results showed that optimum conditions for reaction were obtained:methanol as solvent,mass ratio of methanol to diethyl oxalate=5∶1;molar ratio of diethyl oxalate to monoethanolamine=1∶2.3;reaction temperature=70℃,holding time 1.5h.The yield was 97.1%.
Key words:  N′,N-bis (2-hydroxyethyl) oxamide    synthesis    research
收稿日期:  2017-04-10                出版日期:  2018-08-20      发布日期:  2018-09-18      期的出版日期:  2018-08-20
基金资助: 山东省自然科学基金(ZR2015YL002)
作者简介:  王峰(1981-),男,硕士,主要研究方向为高分子材料合成与应用。
引用本文:    
王峰, 彭丹, 牟秋红, 张方志. N′,N-二-(2-羟乙基)-草酰胺的制备方法研究[J]. 化工新型材料, 2018, 46(8): 195-197.
Wang Feng, Peng Dan, Mu Qiuhong, Zhang Fangzhi. Research on preparation of N′,N-bis(2-hydroxyethyl) oxamide. New Chemical Materials, 2018, 46(8): 195-197.
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http://www.hgxx.org/CN/  或          http://www.hgxx.org/CN/Y2018/V46/I8/195
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