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化工新型材料  2018, Vol. 46 Issue (8): 55-59    
  新材料与新技术 本期目录 | 过刊浏览 | 高级检索 |
三相环氧树脂纳米复合材料的制备及其性能分析
张明艳, 王晨, 吴子剑*, 姜鹏, 高岩
哈尔滨理工大学材料科学与工程学院,哈尔滨150000
Preparation and property of three-phase epoxy nanocomposite
Zhang Mingyan, Wang Chen, Wu Zijian, Jiang Peng, Gao Yan
School of Materials Science and Engineering,Harbin University of Science and Technology,Harbin 150000
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摘要 环氧树脂因韧性差而限制了其在高端领域的应用,为了改善环氧树脂的韧性同时改善环氧树脂的热稳定性,将长径比不同的多壁碳纳米管(MWNTs)进行酸化,对蒙脱土(MMT)进行有机化处理,将MWNTs和MMT共掺杂环氧树脂通过溶液共混法制备三相环氧树脂纳米复合材料。结果表明,当碳纳米管质量分数为1%时,C-MWNTs40-60/O-MMT/EP和C-MWNTs10-20/O-MMT/EP环氧树脂纳米复合材料的冲击强度比未改性的环氧树脂分别提高了107.1%、127.9%,热分解温度比未改性的环氧树脂高20℃、21℃,马丁耐热温度比未改性的环氧树脂高12.4℃、13.8℃。
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张明艳
王晨
吴子剑
姜鹏
高岩
关键词:  环氧树脂  多壁碳纳米管  蒙脱土    
Abstract: Epoxy resin can not be used in high-end application because of its poor toughness.In order to solve the problem and increase the thermal properties of epoxy resin,it was presented that the multi walled carbon nanotubes (MWNTs) with different aspect ratios and montmorillonite (MMT) were treated by acidification and organic treatment respectively.The MWNTs,MMT and epoxy resin were prepared into three-phase epoxy nanocomposite by solution blending method.Results showed that when the carbon nanotubes content was 1(wt)%,the impact strength of C-MWNTs40-60/O-MMT/EP and C-MWNTs10-20/O-MMT/EP were 107.1%,127.9% higher than that of unmodified epoxy resin.The thermal decomposition temperature of C-MWNTs40-60/O-MMT/EP and C-MWNTs10-20/O-MMT/EP were 20℃,21℃ higher than that of unmodified epoxy resin.Martin heat resistant temperature of C-MWNTs40-60/O-MMT/EP and C-MWNTs10-20/O-MMT/EP were 12.4℃,13.8℃ higher than that of unmodified epoxy resin.
Key words:  epoxy resin    multi-walled carbon nanotube    montmorillonite
收稿日期:  2017-04-07                     发布日期:  2018-09-18      期的出版日期:  2018-08-20
基金资助: 黑龙江省博士后面上项目一等资助(LBH-Z16089);中国博士后面上项目一等资助(2017M610212);工程电介质及其应用教育部重点实验室前沿项目预研基金(2018EDAQY05);哈尔滨市科技创新人才(2017RAQXJ105);黑龙江省普通本科高等学校青年创新人才培养计划
通讯作者:  吴子剑(1983-),男,讲师,博士,研究方向为树脂基复合材料。   
作者简介:  张明艳(1962-),女,教授,研究方向为工程电介质材料改性。
引用本文:    
张明艳, 王晨, 吴子剑, 姜鹏, 高岩. 三相环氧树脂纳米复合材料的制备及其性能分析[J]. 化工新型材料, 2018, 46(8): 55-59.
Zhang Mingyan, Wang Chen, Wu Zijian, Jiang Peng, Gao Yan. Preparation and property of three-phase epoxy nanocomposite. New Chemical Materials, 2018, 46(8): 55-59.
链接本文:  
http://www.hgxx.org/CN/  或          http://www.hgxx.org/CN/Y2018/V46/I8/55
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