Development of modified TiO2 photocatalytic water-splitting for hydrogen production
Lu Yanli, Wang Menghuan, Zhang Tinglan, Zhang Wenli, Zeng Xiongfeng
College of Materials Science and Engineering,North China University of Science and Technology,Hebei Provincial Key Laboratory of Inorganic Nonmetallic Materials,Tangshan 063210
Abstract: It is an effective way to produce hydrogen using the modified TiO2 by photocatalytic hydrolysis method.The mechanism of TiO2 photocatalytic water-splitting for hydrogen production and several modification methods of TiO2,such as:metal surface deposition,ion doping,compound semiconductor,light and so on were briefly showed.Finally,the prospect and challenge of photocatalyst for hydrogen evolution were discussed.
路彦丽, 王梦幻, 张汀兰, 张文丽, 曾雄丰. 改性TiO2光催化水解制氢的研究进展[J]. 化工新型材料, 2018, 46(3): 10-13.
Lu Yanli, Wang Menghuan, Zhang Tinglan, Zhang Wenli, Zeng Xiongfeng. Development of modified TiO2 photocatalytic water-splitting for hydrogen production. New Chemical Materials, 2018, 46(3): 10-13.
[1] Fujishima A,Honda K.Electrochemical photolysis of water at a semiconductor electrode[J].Nature,1972,238(5358):37-38. [2] Chen X B,Shen S H,Guo L J,et al.Semiconductor-based photocatalytic hydrogen generation[J].Chemical Reviews,2010,110(11):6503. [3] 高濂,郑珊,张青红.纳米氧化钛光催化材料及应用[M].北京:化学工业出版社,2002,39-52. [4] Kudo A,Miseki Y.Heterogeneous photocatalyst materials for water splitting[J].Chemical Society Reviews,2009,38:253-278. [5] Mizukoshi Y,Makise Y,Shuto T,et al.Immobilization of noble metal nanoparticles on the surface of TiO2 by the sonochemical method:photocatalytic production of hydrogen from an aqueous solution of ethanol[J].Ultrason Sonochem,2007,14(3):387. [6] Su C Y,Liu L,Zhang M Y,et al.Fabrication of Ag-TiO2 nanoheterostructures with visible light photocatalytic function via a solvothermal approach[J].Cryst Eng Comm,2012,14(11):3989-3999. [7] Wang C Z,Chen Z,Jin H B,et al.Enhancing visible-light photoelectrochemical water splitting through transition-metal doped TiO2 nanorodarrays[J].J Mater Chem A,2014,2(42):17820-17827. [8] 刘桢,鲍治宇,董延茂,等.Fe3+掺杂纳米TiO2的表征及其光催化性能的研究[J].安徽农业科学,2011,39(19):11737-11739. [9] 吴道新,陈启元,李洁,等.钨掺杂金红石型二氧化钛的光催化分解水析氧活性[J].中国有色金属学报,2010,20(4):730-735. [10] Yao Z P,Jia F Z,Tian S J,et al.Microporous Ni-doped TiO2 film photocatalyst by plasma electrolytic oxidation[J].ACS InterfacesAmerican Chemical Society,2010,2(9):2617. [11] Asahi R,Morikawa T,Ohwaki T,et al.Visible-light photocatalysis in nitrogen-doped titanium oxides[J].Science,2001,293(5528):269-271. [12] Chaudhari N S,Warule S S,Dhanmane S A,et al.Nanostructured N-doped TiO2 marigold flowers for an efficient solar hydrogen production from H2S[J].Nanoscale,2013,5(19):9383-9390. [13] Niishiro R,Kato H,Kudo A.Nickel and either tantalum or niobium-codoped TiO2 and SrTiO3 photocatalysts with visible-light response for H2 or O2 evolution from aqueous solutions[J].Physical Chemistry Chemical Physics,2005,7(10):2241-2245. [14] Sun X,Liu H,Dong J,et al.Preparation and characterization of Ce/N-codoped TiO2 particles for production of H2 by photocatalytic splitting water under visible light[J].Catalysis Letters,2010,135:219-225. [15] Sun W T,Yu Y,Pan H Y,et al.CdS quantum dots sensitized TiO2 nanotube-array photoelectrodes[J].Journal of the American Chemical Society,2008,130(4):1124-1125. [16] Lee Y L,Chi C F,Liau S Y.CdS/CdSe Co-sensitized TiO2 photoelectrode for efficient hydrogen generation in a photoelectrochemical cell[J].Chemistry of Materials,2010,22(3):922-927. [17] Li K,Chai B,Peng T,et al.Preparation of AgIn5S8/TiO2 heterojunction nanocomposite and its enhanced photocatalytic H2 production property under visible light[J].ACS Catalysis,2013,3(2):170-177. [18] Fu Ning,Lv Gongxuan.Photosensitization of heteropoly blue for TiO2 under visible light irradiation[J].Acta Chimica Sinica,2007,65(14):1325-1332. [19] 钮金芬,姚秉华,余晓皎,等.锌卟啉敏化TiO2光催化剂的原位法制备及其光催化性能研究[J].功能材料,2013,44(8):1132-1135. [20] Roy N,Sohn Y,Pradhan D.Synergy of low-energy {101} and high-energy {001} TiO2 crystal facets for enhanced photocatalysis[J].ACS Nano,2013,7(3):2532-2540. [21] Bard A J.Photoelectrochemistry and heterogeneous photocatalysis at semiconductors[J].Journal of Photochemistry,1979,10(1):59-75. [22] Ma S S K,Hisatomi T,Domen K.Hydrogen production by photocatalytic water splitting[J].Bulletin of the Japan Petroleum Institute,2013,56(5):280-287. [23] Yun H J,Lee H,Kim N D,et al.A combination of two visible-light responsive photocatalysts for achieving the Z-scheme in the solid state[J].Acs Nano,2011,5(5):4084-4090.