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化工新型材料  2018, Vol. 46 Issue (8): 15-19    
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金属有机骨架化合物作为高能钝感材料的研究进展
张恒宁, 常海*, 齐晓飞
西安近代化学研究所,西安710065
Research progress of metal organic framework (MOFs) as high energy insensitive material
Zhang Hengning, Chang Hai, Qi Xiaofei
Xi´an Modern Chemistry Research Institute,Xi´an 710065
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摘要 通过配位化学合成得到的金属有机骨架化合物(MOFs)在气体贮存、分子分离、催化以及药物缓释等领域具有广阔的应用前景。近年来,MOFs在含能材料领域,特别是在高能钝感材料领域的应用潜力日益突出。按照MOFs空间骨架结构的分类,分别综述了一维、二维以及三维MOFs材料的合成及表征,着重讨论了不同空间结构的MOFs材料所具有的能量特性和钝感特性。可以预见,含能MOFs将为设计与合成新一代高能、低感度的绿色含能材料提供一个崭新的研究思路。
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张恒宁
常海
齐晓飞
关键词:  配位化学  金属有机骨架化合物  高能  钝感  空间结构    
Abstract: Metal organic framework (MOFs) obtained through coordination chemistry synthesis has a wide application potential in fields of gas reservation,molecular isolation,catalysis and drug sustained release.In recent years,MOFs has a growing potential in energetic materials fields,especially in high energy insensitive filler.According to the classification of space structure of MOFs,the synthesis and characterization of one-dimensional,two-dimensional and three-dimensional MOFs were reviewed.The discussion on energy features and insensitive features with different structure were highlighted.It is expected that energetic MOFs can provide a whole new solution on designing and synthesizing the new generation of high-energy,low-sensitivity and green energetic materials.
Key words:  coordination chemistry    metal organic framework    high energy    low sensitivity    spatial structure
收稿日期:  2017-03-30                     发布日期:  2018-09-18      期的出版日期:  2018-08-20
基金资助: 总装备部预先研究项目(004040204)
通讯作者:  常海(1962-),男,博士,研究员,主要从事固体推进剂研究。   
作者简介:  张恒宁(1985-),男,博士研究生,主要从事固体推进剂研究。
引用本文:    
张恒宁, 常海, 齐晓飞. 金属有机骨架化合物作为高能钝感材料的研究进展[J]. 化工新型材料, 2018, 46(8): 15-19.
Zhang Hengning, Chang Hai, Qi Xiaofei. Research progress of metal organic framework (MOFs) as high energy insensitive material. New Chemical Materials, 2018, 46(8): 15-19.
链接本文:  
http://www.hgxx.org/CN/  或          http://www.hgxx.org/CN/Y2018/V46/I8/15
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