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化工新型材料  2018, Vol. 46 Issue (10): 79-82    
  新材料与新技术 本期目录 | 过刊浏览 | 高级检索 |
紫外光固化十二烷基苯磺酸掺杂的 纳米聚苯胺/环氧丙烯酸树脂 互穿网络导电复合膜的制备及性能
郑鑫1,母章1,谭晓明2
1.新疆维吾尔自治区地质矿产勘查开发局地球物理化学探矿大队,昌吉831100;
2.荆楚理工学院,荆门448000
Preparation and property of UV-curable PANI-DBSA/EA interpenetrating network conductive composite membrane
Zheng Xin1,Mu Zhang1,Tan Xiaoming2
1.Department of Geophysical and Geochemical Exploration,Bureau of Geology and Mineral Exploration and Development of Xinjiang Uygur Autonomous Region,Changji 831100;
2.Jingchu University of Technology,Jingmen 448000
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摘要 采用原位乳液聚合法合成了十二烷基苯磺酸掺杂的纳米聚苯胺/环氧丙烯酸树脂(PNAI-DBSA/EA)混合物,加入活性稀释剂、引发剂等搅拌混合均匀后,在紫外光照下固化形成纳米PNAI-DBSA/EA互穿网络导电复合膜。通过凝胶含量和电导率的测定,研究了活性稀释剂、引发剂、光照时间和PANI-DBSA含量等因素对复合膜性能的影响。结果表明:在PANI-DBSA含量为15%(wt,质量分数,下同)、引发剂2,4,6-二苯基氧化膦为4%,固化时间为40s,活性稀释剂乙氧基化三羟甲基丙烷三丙烯酸酯为50%时,导电膜凝胶含量达91.8%,导电率为8×10-6S/m。
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郑鑫
母章
谭晓明
关键词:  聚苯胺  环氧丙烯酸树脂  互穿网络  光固化  导电    
Abstract: The nano-polyaniline/epoxy acrylate (PANI-DBSA/EA) mixture was synthesized by in-situ emulsion polymerization.Then it was added that diluted crosslinking monomer and initiating agent with stirring until well-distributed.At last,PANI-DBSA/EA interpenetrating networks conductive film was prepared through UV curing.The influence of crosslinking monomer,initiator,cure time and PANI-DBSA to the film's gel content and conductivity was investigated.The results showed that the gel content of film reached 91.8% and the conductivity was 8×10-6S/m when the content of PANI-DBSA was 15wt%,the initiating agent dosage of TPO was 4wt%,the content of crosslinking monomer EO-TMPTA was 50wt% and the curing time was 40s.
Key words:  polyaniline    epoxy acrylate (EA)    interpenetrating network    UV-curing    electric conduction
                    发布日期:  2018-11-06      期的出版日期:  2018-11-06
作者简介:  郑鑫(1986-),女,实验测试工程师,主要从事高分子材料研究。
引用本文:    
郑鑫,母章,谭晓明. 紫外光固化十二烷基苯磺酸掺杂的 纳米聚苯胺/环氧丙烯酸树脂 互穿网络导电复合膜的制备及性能[J]. 化工新型材料, 2018, 46(10): 79-82.
Zheng Xin,Mu Zhang,Tan Xiaoming. Preparation and property of UV-curable PANI-DBSA/EA interpenetrating network conductive composite membrane. New Chemical Materials, 2018, 46(10): 79-82.
链接本文:  
http://www.hgxx.org/CN/  或          http://www.hgxx.org/CN/Y2018/V46/I10/79
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