Abstract: Photo-degradation catalysts have many advantages in the application of degrading organic pollutants in air and water:low cost,high efficient,can be recycled and processed with no secondary pollution,etc.and show the application prospects in the strategy of sustainable development.A variety of new photodegradation catalysts and their applications were briefly described,and the problems that need to be solved in the future development of photodegradation catalysts were analyzed.It was pointed out that photo-degradation nano-composite catalysts had great potential to deal with actual pollution system.
李子成,杨涛,陆丽晨,周维君,韩书广. 光降解催化剂及其应用研究进展[J]. 化工新型材料, 2018, 46(10): 57-62.
Li Zicheng,Yang Tao,Lu Lichen,Zhou Weijun,Han Shuguang. Current research status of photo-degradation catalyst and its application. New Chemical Materials, 2018, 46(10): 57-62.
[1] Gogate P R,Pandit A B.A review of imperative technologies for wastewater treatment Ⅰ:oxidation technologies at ambient conditions[J].Advances in Environmental Research,2004,8(3/4):501-551. [2] 王俊,张景义,陈双基.室内空气中总挥发性有机物(TVOCs)的污染[J].北京联合大学学报,2002,27(3):52-56. [3] Maciej D,Pawei Z,Anna K,et al.Photocatalytic degradation of sulfamethoxazole in aqueous solution using a floating TiO2-expanded perlite photocatalyst[J].Journal of Hazardous Materials,2015,298:146-153. [4] Xekoukoulotakis N P,Drosou C,Brebou C,et al.Kinetics of UV-A/TiO2 photocatalytic degradation and mineralization of the antibiotic sulfamethoxazole in aqueous matrices[J].Catalysis Today,2011,161(1):163-168. [5] Abelln M N,Giménez J,Esplugas S.Photocatalytic degradation of antibiotics:the case of sulfamethoxazole and trimethoprim[J].Catalysis Today,2009,144(1):131-136. [6] Beltrn F J,Aguinaco A,García-Araya J F.Mechanism and kinetics of sulfamethoxazole photocatalytic ozonation in water[J].Water Research,2009,43(5):1359-1369. [7] Yang H,An T C,Li G Y,et al.Photocatalytic degradation kinetics and mechanism of environmental pharmaceuticals in aqueous suspension of TiO2:a case of sulfa drugs[J].Journal of Hazardous Materials,2010,153(3/4):200-207. [8] Lin H,Niu J,Xu J,et al.Electrochemical mineralization of sulfamethoxazole by Ti/SnO2-Sb/Ce-PbO2 anode:kinetics,reaction pathways,and energy cost evolution[J].Electrochimica Acta,2013,97(5):167-174. [9] 赵国华,谢栋,耿政松,等.高浓度臭氧用于污水处理的研究[J].工业水处理,2002,22(9):1-5. [10] Baran W,Sochacka J,Wardas W.Toxicity and biodegradability of sulfonamides and products of their photocatalytic degradation in aqueous solutions[J].Chemosphere,2006,65(8):1295-1299. [11] Sirés I,Brillas E,Oturan M A,et al.Electrochemical advanced oxidation processes:today and tomorrow.A review[J].Environ Sci Pollut Res Int,2014,21(14):8336-8367. [12] Sun J,Yan X,Lv K,et al.Photocatalytic degradation pathway for azo dye in TiO2/UV/O3 system:hydroxyl radical versus hole[J].Journal of Molecular Catalysis A Chemical,2013,367(2):31-37. [13] Fujishima A,Honda K.Electrochemical photolysis of water at a semiconductor electrode[J].Nature,1972,238(238):37-38. [14] Frank S N,Bard A J.Heterogeneous photocatalytic oxidation of cyanide and sulfite in aqueous solutions at semiconductor powders[J].The Journal of Physical Chemistry,1977,15(81):1484-1488. [15] Kraeutler B,Bard A J.Heterogeneous photocatalytic decomposition of saturated carboxylic acids on titanium dioxide powder.decarboxylative route to alkanes[J].Journal of the American Chemical Society,1978,100(19):5985-5992. [16] 王晓燕,冀志江,王静,等.光催化剂新技术及研究进展[J].材料导报,2008,22(10):40-44. [17] Gaya U I,Abdullah A H.Heterogeneous photocatalytic degradation of organic contaminants over titanium dioxide:a review of fundamentals,progress and problems[J].Journal of Photochemistry & Photobiology C Photochemistry Reviews,2008,9(1):1-12. [18] Wilke K,Breuer H D.The influence of transition metal doping on the physical and photocatalytic properties of titania[J].Journal of Photochemistry & Photobiology A Chemistry,1999,121(1):49-53. [19] Bickley R I,Gonzalez-carreno T,Lees J S,et al.A structural investigation of titanium dioxide photocatalysts[J].Journal of Solid State Chemistry,1991,92(1):178-190. [20] 王家恒,宫长伟,付现凯,等.TiO2光催化剂的掺杂改性及应用研究进展[J].化工新型材料,2016,44(1):15-18. [21] Fu H,Pan C,Wenqing Y,et al.Visible-light-induced degradation of rhodamine B by nanosized Bi2WO6[J].Journal of Physical Chemistry B,2008,109(47):22432-22439. [22] He D,Wang L,Li H,et al.Self-assembled 3D hierarchical clew-like Bi2WO6 microspheres:synthesis,photo-induced charges transfer properties,and photocatalytic activities[J].Crystengcomm,2011,13(12):4053-4059. [23] Fraga L E,Franco J H,Orlandi M,et al.Photoelectrocatalytic oxidation of hair dye basic red 51 at W/WO3/TiO2 bicomposite photoanode activated by ultraviolet and visible radiation[J].Journal of Environmental Chemical Engineering,2013,1(3):194-199. [24] Liu Y G,Ohko Y,Zhang R,et al.Degradation of malachite green on Pd/WO3 photocatalysts under simulated solar light[J].Journal of Hazardous Materials,2010,184(1/3):386-391. [25] Ma S S K,Maeda K,Abe R,et al.Visible-light-driven nonsacrificial water oxidation over tungsten trioxide powder modified with two different cocatalysts[J].Energy & Environmental Science,2012,5(8):8390-8397. [26] Tsukasa T,Nakamura N,Ikeda S,et al.Discrimination of the active crystalline phases in anatase rutile mixed titanium(ⅳ) oxide photocatalysts through action spectrum analyses[J].Physical Chemistry Chemical Physics,2002,4(23):5910-5914. [27] Miyauchi M.Photocatalysis and photoinduced hydrophilicity of WO3 thin films with underlying Pt nanoparticles[J].Physical Chemistry Chemical Physics,2008,10(41):6258-6265. [28] Wang T,Quan W,Jiang D,et al.Synthesis of redox-mediator-free direct Z-scheme AgI/WO3 nanocomposite photocatalysts for the degradation of tetracycline with enhanced photocatalytic activity[J].Chemical Engineering Journal,2016,300(15):280-290. [29] Shen G Z,Bando Y,Liu B D,et al.Characterization and field-emission properties of vertically aligned ZnO nanonails and nanopencils fabricated by a modified thermal-evaporation process[J].Advanced Functional Materials,2005,16(3):410-416. [30] Romero M,Blanco J,Sanchez B,et al.Solar photocatalytic degradation of water and air pollutants:challenges and perspectives[J].Solar Energy,1999,66(2):169-182. [31] Awasthi G P,Adhikari S P,Ko S,et al.Facile synthesis of ZnO flowers modified graphene like MoS2 sheets for enhanced visible-light-driven photocatalytic activity and antibacterial properties[J].Journal of Alloys & Compounds,2016,682:208-215. [32] Abbasi A,Ghanbari D,Salavati-Niasari M,et al.Photo-degradation of methylene blue:photocatalyst and magnetic investigation of Fe2O3-TiO2 nanoparticles and nanocomposites[J].Journal of Materials Science:Materials in Electronics,2016,27(5):1-10. [33] Hashimoto K,Irie H,Fujishima A.Historical overview and future prospects[J].Clinical & Experimental Metastasis,1996,14(1):9-19. [34] Hui W,Wang H L,Jiang W F,et al.Photocatalytic degradation of 2,4-dinitrophenol (DNP) by multi-walled carbon nanotubes (MWCNTs)/TiO2 composite in aqueous solution under solar irradiation[J].Water Research,2009,43(1):204-210. [35] 林立,袁点,邓怡玄,等.BiOBr/BiOI-FACs催化剂的组装与光催化性能[J].硅酸盐通报,2015,34(12):3581-3585. [36] 练涛,林远,梁少强,等.Fe3O4/G-BiOCl纳米复合光催化剂的制备及光催化性能研究[J].化工新型材料,2017,45(2):162-164. [37] 刘谋圳,从宪玲,蒲锡鹏,等.g-C3N4/Ag/AgCl/TiO2复合材料的制备及其光催化性能研究[J].化工新型材料,2016,44(7):93-95. [38] 孙钰琨,白波,王红伦,等.NiO/In2O3 p-n结型光催化剂的制备及其降解盐酸强力霉素研究[J].化学工程,2016,44(6):26-31. [39] 叶林静,安小英,姜韵婕,等.ZnO/CdS复合光催化剂的制备及降解四环素类抗生素[J].化工进展,2015,34(11):3944-3950. [40] Jamali A,Vabraes R,Hanselaer P,et al.A batch LED reactor for the photocatalytic degradation of phenol[J].Chemical Engineering & Processing Process Intensification,2013,71(9):43-50. [41] Lachheb H,Puzenat E,Houas A,et al.Photocatalytic degradation of various types of dyes in water by UV-irradiated titania[J].Applied Catalysis B Environmental,2002,39(1):75-90. [42] 邱天,杨浩.银修饰钒酸铋的制备及其催化性能研究[J].广东化工,2016,43(9):14-15. [43] Levchuk I,Rueda-marquez J J,Suihkonen S,et al.Application of UVA-LED based photocatalysis for plywood mill wastewater treatment[J].Separation & Purification Technology,2015,143(25):1-5. [44] Dai K,Peng T,Chen H,et al.Photocatalytic degradation and mineralization of commercial methamidophos in aqueous titania suspension[J].Environmental Science & Technology,2008,42(5):1505-1510. [45] Gar A M,Ookawara S,Fukushi D,et al.Improved WO3 photocatalytic efficiency using ZrO2 and Ru for the degradation of carbofuran and ampicillin[J].Journal of Hazardous Materials,2015,302(2):225-231. [46] Vulliet E,Emmelin C,Chovelon J M,et al.Photocatalytic degradation of sulfonylurea herbicides in aqueous TiO2[J].Applied Catalysis B Environmental,2002,38(2):127-137. [47] 安小英,蔡漪,姜韵婕,等.g-C3N4/HNTs复合光催化剂的制备及其降解盐酸四环素研究[J].化工新型材料,2017,45(5):161-163. [48] 洪伟,古国榜,吴志伟,等.光催化氧化法治理恶臭污染的工程应用[J].环境工程,2002,20(6):40-42. [49] 黄勇,陈江耀,李建军,等.生物滴滤塔耦合光催化氧化技术处理电子垃圾拆解车间排放废气的中试研究[J].生态环境学报,2014,23(5):817-823. [50] 邵振华,魏博伦,叶志平,等.等离子体联合光催化治理喷漆废气[J].浙江大学学报(工学版),2014,48(6):1127-1131. [51] 鱼惟铭.光催化氧化与吸附组合工艺处理C5树脂生产装置污水站废气[J].环境与发展,2014,2014(1/2):142-144. [52] Tongon W,Chawengkijwanich C,Chiarakorn S.Multifunctional Ag/TiO2/MCM-41 nanocomposite film applied for indoor air treatment[J].Building & Environment,2014,82:481-489. [53] 匡亚川,张召环,季小勇,等.具有降解汽车尾气性能的纳米TiO2光催化水泥浆体研究[J].功能材料,2017,48(2):02241-02245. [54] Chen H,Tang P,Pan G,et al.Preparation of Ag/TiO2/PA self-cleaning paint by in-suit polymerization and its antimicrobial properties[J].Rare Metal Materials & Engineering,2012,41(11):254-257. [55] Sekiguchi Y,Yao Y Y,Ohko Y,et al.Self-sterilizing catheters with titanium dioxide photocatalyst thin films for clean intermittent catheterization:basis and study of clinical use[J].International Journal of Urology,2007,14(5):426-430.