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化工新型材料  2018, Vol. 46 Issue (10): 187-189    
  科学研究 本期目录 | 过刊浏览 | 高级检索 |
生物质聚异山梨醇碳酸酯的合成方法 及其性能研究
封东廷,单玉华*,王超,刘入强,黄超
常州大学,江苏省先进催化与绿色制造协同创新中心,常州213164
Synthesis and property of poly (isosobide carbonate) derived from biomass
Feng Dongting, Shan Yuhua, Wang Chao ,Liu Ruqiang ,Huang Chao
Advanced Catalysis and Green Manufacturing Collaborative Innovation Center, Changzhou University,Changzhou 213164
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摘要 采用新的合成方法,以异山梨醇(IS)和氯甲酸三氯甲酯(TCF)为原料,合成了高相对分子质量的生物质聚异山梨醇碳酸酯(PIC),考察了原料配比和反应温度对产品相对分子质量的影响。采用傅里叶变换红外光谱仪、核磁共振氢谱仪、热重分析仪和凝胶渗透色谱仪分别对产物的结构、热稳定性和相对分子质量进行了表征。结果表明:在IS与TCF摩尔比为1∶0.59,反应温度5℃的条件下,合成的PIC数均分子量(Mn)达到53172(远高于用碳酸二苯酯合成的Mn 18300),玻璃化转变温度为118℃,失重5%时热分解温度为326℃,产品透明度良好、热稳定性高。
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封东廷
单玉华
王超
刘入强
黄超
关键词:  异山梨醇  氯甲酸三氯甲酯  聚异山梨醇碳酸酯  合成  性能    
Abstract: A high molecular weight poly (isosobide carbonate) (PIC) derived from biomass was synthesized with a new method using isosorbide (IS) and trichloromethyl chloroformate (TCF) as raw materials.The influences of reaction temperature and raw materials ratio on the molecular weight of PIC were investigated.FT-IR,1H-NMR,thermogravimetric (TG) and gel permeation chromatography (GPC) were used to characterize the structure,thermostability and molecular weight of products.The results showed that when the molar ratio of IS and TCF as 1∶0.59,reacting at 5℃,the number average molecular weight(Mn) of PIC was up to 53172(far higher than reported data of 18300) with a Tg of 118℃ and Td,5% of 326℃,exhibited good transparency and thermostability.
Key words:  isosorbide    trichloromethyl chloroformate    poly(isosobide carbonate)    synthesis    property
               出版日期:  2018-10-20      发布日期:  2018-11-06      期的出版日期:  2018-10-20
通讯作者:  单玉华(1963-),男,教授,研究生导师,主要研究方向为绿色催化。   
作者简介:  封东廷(1992-),男,硕士研究生,主要研究方向为有机化学。
引用本文:    
封东廷,单玉华,王超,刘入强,黄超. 生物质聚异山梨醇碳酸酯的合成方法 及其性能研究[J]. 化工新型材料, 2018, 46(10): 187-189.
Feng Dongting, Shan Yuhua, Wang Chao ,Liu Ruqiang ,Huang Chao. Synthesis and property of poly (isosobide carbonate) derived from biomass. New Chemical Materials, 2018, 46(10): 187-189.
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http://www.hgxx.org/CN/  或          http://www.hgxx.org/CN/Y2018/V46/I10/187
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